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CBSE Class 12 Chemistry 2014 Delhi Set 1 Solved Paper

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Question : 27 of 30
Marks: +1, -0
Give the structures of A,BA, B and CC in the following reactions:
(i) CH3BrKCNALiAlH4BHNO2C\mathrm{CH}_3\mathrm{Br} \xrightarrow{\mathrm{KCN}} A \xrightarrow{\mathrm{LiAlH}_4} B \xrightarrow{\mathrm{HNO}_2} C
(ii) CH3COOHNH3ABr2+KOHB\mathrm{CH}_3\mathrm{COOH} \xrightarrow{\mathrm{NH}_3} A \xrightarrow{\mathrm{Br}_2+\mathrm{KOH}} B CHCl3+NaOHC\xrightarrow{\mathrm{CHCl}_3+\mathrm{NaOH}} C
OR
How will you convert the following?
(i) Nitrobenzene into aniline.
(ii) Ethanoic acid into methanamine.
(iii) Aniline into N-phenylethanamide.
(Write the chemical equations involved.)
Solution:  
(i) CH3BrKCNCH3CNLiAlH4CH3CH2NH2\mathrm{CH}_3\mathrm{Br} \xrightarrow{\mathrm{KCN}} \mathrm{CH}_3\mathrm{CN} \xrightarrow{\mathrm{LiAlH}_4} \mathrm{CH_3CH_2NH_2} HNO2CH3CH2OH\xrightarrow{\mathrm{HNO}_2} \mathrm{CH_3CH_2OH}
(ii) CH3COOHNH3CH3CONH2Br2+KOHCH3NH2\mathrm{CH}_3\mathrm{COOH} \xrightarrow{\mathrm{NH}_3} \mathrm{CH_3CONH_2} \xrightarrow{\mathrm{Br}_2+\mathrm{KOH}} \mathrm{CH_3NH_2} CHCl3+NaOHCH3NC\xrightarrow{\mathrm{CHCl}_3+\mathrm{NaOH}} \mathrm{CH_3N\equiv C}
OR
(i) Nitrobenzene into aniline
(ii) Ethanoic acid to methenamine
CH3COOHNH3CH3CONH2Br2+KOHCH3NH2\mathrm{CH}_3\mathrm{COOH} \xrightarrow{\mathrm{NH}_3} \mathrm{CH}_3\mathrm{CONH}_2 \xrightarrow{\mathrm{Br}_2+\mathrm{KOH}} \mathrm{CH}_3\mathrm{NH}_2
(iii) Aniline into N-phenylethaneamide
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