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CBSE Class 12 Chemistry 2016 Delhi Set 1 Solved Paper

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Question : 24 of 26
Marks: +1, -0
Account for the following:
(i) Ozone is thermodynamically unstable.
(ii) Solid PCl5\mathrm{PCl}_5 is ionic in nature.
(iii) Fluorine forms only one oxoacid HOF.
(b) Draw the structure of
(i) BrF5\mathrm{BrF}_5
(ii) XeF4\mathrm{XeF}_4
OR
(i) Compare the oxidising action of F2\mathrm{F}_2 and Cl2\mathrm{Cl}_2 by considering parameters such as bond dissociation enthalpy, electron gain enthalpy and hydration enthalpy.
(ii) Write the conditions to maximize the yield of H2SO4\mathrm{H}_2\mathrm{SO}_4 by contact process.
(iii) Arrange the following in the increasing order of property mentioned :
(a) H3PO3,    H3PO4,    H3PO2    \mathrm{H}_3\mathrm{PO}_3, \;\; \mathrm{H}_3\mathrm{PO}_4, \;\; \mathrm{H}_3\mathrm{PO}_2 \;\; (Reducing character).
(b) NH3,    PH3,    AsH3,    SbH3,    BiH3\mathrm{NH}_3, \;\; \mathrm{PH}_3, \;\; \mathrm{AsH}_3, \;\; \mathrm{SbH}_3, \;\; \mathrm{BiH}_3 (Base strength).
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