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CBSE Class 12 Chemistry 2017 Delhi Set 1 Solved Paper

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Question : 18 of 26
Marks: +1, -0
Write structures of compounds A,BA, B and CC in each of the following reaction:
(i) C6H5BrMg/ dry ether A (b) H3O+(a)CO2(g)BPCl3C\mathrm{C}_6\mathrm{H}_5\mathrm{Br} \xrightarrow{\mathrm{Mg} / \text{ dry ether }} A \xrightarrow[\text{ (b) } \mathrm{H}_3\mathrm{O}^+]{(a) \mathrm{CO}_{2(g)}} B \xrightarrow{\mathrm{PCl}_3} C BPCl3CB \xrightarrow{\mathrm{PCl}_3} C
(ii) CH3CN (b) H3O+(a)SnCl2/HClA dil. NaOHB\mathrm{CH}_3\mathrm{CN} \xrightarrow[\text{ (b) } \mathrm{H}_3\mathrm{O}^+]{(a) \mathrm{SnCl}_2 / \mathrm{HCl}} A \xrightarrow{\text{ dil. } \mathrm{NaOH}} B Δ C \xrightarrow{\Delta} \text{ C }
OR
Do the following conversions in not more than two steps:
(i) Benzoic acid to benzaldehyde
(ii) Ethyl benzene to benzoic acid
(iii) Propanone to propene
Solution:  
OR
(iii) CH3COCH3PropanoneLiAlH4\underset{\text{Propanone}}{\mathrm{CH}_3-\overset{\mathrm{O}}{\overset{\parallel}{\mathrm{C}}}-\mathrm{CH}_3} \xrightarrow{\mathrm{LiAlH}_4} CH3CHOHCH3H2SO4\mathrm{CH}_3 \overset{\mathrm{OH}}{\overset{\vert}{\mathrm{CH}}} - \mathrm{CH}_3 \xrightarrow{\mathrm{H}_2\mathrm{SO}_4} CH3CH=CH2Propene\underset{\text{Propene}}{\mathrm{CH}_3\mathrm{CH}=\mathrm{CH}_2}
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