(i) $\{R\}$ is reflexive if it contains $\{(1,1),(2,2)$ and $(3,3)\}$. Since, $(2,2) \in R$. So, we need to add $(1,1)$ and $(3,3)$ to make $R$ reflexive.(ii) $\{R\}$ is symmetric if it contains $\{(2,2),(1,3),(3,1),(3,2)$, $(2,3)\}$.Since, $\{(2,2),(1,3),(3,2)\} \in R$. So, we need to add $(3,1)$ and $(2,3)$.Thus, minimum ordered pairs which should be added in relation $\{R\}$ to make it reflexive and symmetric are $\{(1,1),(3,3),(3,1),(2,3)\}$.