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NCERT Class XI Chemistry Environmental Chemistry Solutions

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Question : 9 of 20
Marks: +1, -0
What are the reactions involved for ozone layer depletion in the stratosphere?
Solution:  
(i) The main reason for ozone layer depletion besides other gases are chlorofluorocarbons (CFCs).
(ii) Once CFCs are released into the atmosphere, they reach the stratosphere and release free-radicals by the action of sunlight.
CF2Cl2(g)\mathrm{CF}_2\mathrm{Cl}_{2(g)} →UV\xrightarrow{UV} Cl(g)⋅+C.F2Cl(g)\mathrm{Cl}_{(g)}^{\cdot}+\overset{.}{\mathrm{C}}\mathrm{F}_2\mathrm{Cl}_{(g)}
(iii) These radicals further react with ozone and bring about its depletion.
Cl(g)⋅+O3(g)\mathrm{Cl}_{(g)}^{\cdot}+\mathrm{O}_{3(g)} → ClO(g)⋅+O2(g)\mathrm{ClO}_{(g)}^{\cdot}+\mathrm{O}_{2(g)}
O3(g)\mathrm{O}_{3(g)} ⇌UV\overset{\text{UV}}{\rightleftharpoons} O2(g)+O(g)\mathrm{O}_{2(g)}+\mathrm{O}_{(g)}
ClO(g)⋅+O(g)\mathrm{ClO}_{(g)}^{\cdot}+\mathrm{O}_{(g)} → Cl(g)⋅+O2(g)\mathrm{Cl}_{(g)}^{\cdot}+\mathrm{O}_{2(g)}
(iv) Such regeneration of Cl.\overset{.}{\mathrm{Cl}} radicals, causes continuous eating away of the O3\mathrm{O}_3 layer creating ozone holes.
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