Test Index

NCERT Class XI Chemistry Redox Reactions Solutions

© examsnet.com
Question : 17 of 30
Marks: +1, -0
Consider the reactions :
(a) H3PO2(aq)+4AgNO3(aq)+2H2O(l)\mathrm{H_3PO_{2(aq)}} + 4\mathrm{AgNO_3}_{(aq)} + 2\mathrm{H_2O}_{(l)}H3PO4(aq)+4Ag(s)+4HNO3(aq)\mathrm{H_3PO_4}_{(aq)} + 4\mathrm{Ag}_{(s)} + 4\mathrm{HNO_3}_{(aq)}
(b) H3PO2(aq)+2CuSO4(aq)+2H2O(l)\mathrm{H_3PO_2}_{(aq)} + 2\mathrm{CuSO_4}_{(aq)} + 2\mathrm{H_2O}_{(l)}H3PO4(aq)+2Cu(s)+H2SO4(aq)\mathrm{H_3PO_4}_{(aq)} + 2\mathrm{Cu}_{(s)} + \mathrm{H_2SO_4}_{(aq)}
(c)
C6H5CHO(l)+2[Ag(NH3)2](aq)++3OH(aq)\mathrm{C_6H_5CHO}_{(l)} + 2\mathrm{[Ag(NH_3)_2]}^{+}_{(aq)} + 3\mathrm{OH}^{-}_{(aq)}
C6H5COO(aq)+2Ag(s)+4NH3(aq)+2H2O(l)\mathrm{C_6H_5COO}^{-}_{(aq)} + 2\mathrm{Ag}_{(s)} + 4\mathrm{NH_3}_{(aq)} + 2\mathrm{H_2O}_{(l)}
(d)
C6H5CHO(l)+2Cu(aq)2++5OH(aq)\mathrm{C_6H_5CHO}_{(l)} + 2\mathrm{Cu}^{2+}_{(aq)} + 5\mathrm{OH}^{-}_{(aq)}
→ No change observed.
What inference do you draw about the behaviour of Ag+\mathrm{Ag}^{+} and Cu2+\mathrm{Cu}^{2+} from these reactions ?
Solution:  
Reactions (a) and (b) indicate that both AgNO3\mathrm{AgNO_3} and CuSO4\mathrm{CuSO_4} oxidise H3PO2\mathrm{H_3PO_2} to H3PO4\mathrm{H_3PO_4}. Hence, both are oxidising agents.
Reactions (c) and (d) suggest that [Ag(NH3)2]+\mathrm{[Ag(NH_3)_2]}^{+} oxidises C6H5CHO\mathrm{C_6H_5CHO} (benzaldehyde) to C6H5COO\mathrm{C_6H_5COO}^{-} (benzoate ion) but Cu2+\mathrm{Cu}^{2+} ions cannot oxidise C6H5CHO\mathrm{C_6H_5CHO} to C6H5COO\mathrm{C_6H_5COO}^{-}. Therefore, from the above reactions, we infer that Ag+\mathrm{Ag}^{+} ion is a stronger oxidising agent than Cu2+\mathrm{Cu}^{2+} ion.
© examsnet.com
Go to Question: