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NCERT Class XI Chemistry The p-Block Elements Solutions
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Question : 14 of 38
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Suggest reasons why the B—F bond lengths in (130 pm) and (143 pm) differ.
Solution:
The bond length in any compound is dependent on the hybridisation of the central atom. Boron in is hybridised which means that the s-character is 33% and therefore, the bond length is shorter. Also due to similar size of both atoms and vacant p-orbital of B, a pp-pp back bonding from F to B occurs causes partial double bond character. This further decreases the bond length of B — F. In , the hybridisation of B is which means that the s-character is 25% and therefore, a longer bond length.
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