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NCERT Class XI Chemistry The p-Block Elements Solutions
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Question : 21 of 38
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Explain the following reactions : (a) Silicon is heated with methyl chloride at high temperature in the presence of copper; (b) Silicon dioxide is treated with hydrogen fluoride; (c) CO is heated with ZnO; (d) Hydrated alumina is treated with aqueous NaOH solution.
Solution:
(a) When methyl chloride reacts with silicon in the presence of copper as a catalyst at a temperature 573 K various types of methyl substituted chlorosilane of formula with small amount of are formed. + (b) When silicon dioxide is treated with HF, silicon tetrafluoride is formed. → (c) CO is a powerful reducing agent, it reduces ZnO to Zn. ↑ (d) Aluminium reacts with aqueous alkali and liberates hydrogen gas. → ↑
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