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Question : 9 of 14
Marks: +1, -0
At what temperature is the root mean square speed of an atom in an argon gas cylinder equal to the rms speed of a helium gas atom at –20°C? (atomic mass of Ar = 39.9 u, of He = 4.0 u).
Solution:  
Here, atomic mass of argon M1=39.9M_1 = 39.9
Atomic mass of helium He = 4.0
Let C1C_1 and C2C_2 be the rms velocities of argon and helium at temperature T1T_1 K and T2T_2 K respectively.
We know that rms speed is given by
C=3RTMC=\sqrt{\frac{3RT}{M}} ;
C1=3RT1M1=3RT39.9C_{1}=\sqrt{\frac{3RT_{1}}{M_{1}}}=\sqrt{\frac{3RT}{39.9}} ;
C2=3RT2M=3R×2534C_{2}=\sqrt{\frac{3RT_{2}}{M}}=\sqrt{\frac{3R \times 253}{4}}
Since C1=C2C_1 = C_2
3RT39.9=3R×2534\sqrt{\frac{3RT}{39.9}}=\sqrt{\frac{3R \times 253}{4}}
T=39.9×2534=2523.7K\Rightarrow T=\frac{39.9 \times 253}{4}=2523.7\,\text{K}
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