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NCERT Class XII Chapter
Nuclei
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Question : 22 of 31
Marks: +1, -0
For the β+\beta^{+} (positron) emission from a nucleus, there is another competing process known as electron capture (electron from an inner orbit, say, the K-shell, is captured by the nucleus and a neutrino is emitted).
e++ZAXe^{+} + \,{}^{A}_{Z}XZ1AY+v\,{}^{A}_{Z-1}Y + v
Show that if β+\beta^{+} emission is energetically allowed, electron capture is necessarily allowed but not vice-versa.
Solution:  
Let us first consider positron emission.
ZAX\,{}^{A}_{Z}XZ1AY+e+\,{}^{A}_{Z-1}Y + e^{+} + v + Q1Q_1
The Q value is
Q1Q_1 = [m(ZAX)m(Z1AY)me]c2\left[ m\left( \,{}^{A}_{Z}X \right) - m\left( \,{}^{A}_{Z-1}Y \right) - m_e \right] c^2 ... (i)
Let us now consider electron capture
e+ZAXe^{-} + \,{}^{A}_{Z}XZ1AY\,{}^{A}_{Z-1}Y + v + Q2Q_2
The Q value
Q2Q_2 = [m(ZAX)+mem(Z1AY)]c2\left[ m\left( \,{}^{A}_{Z}X \right) + m_e - m\left( \,{}^{A}_{Z-1}Y \right) \right] c^2
So , Q2Q_2 > Q1Q_1
This mean if Q1Q_1 > 0 then Q2Q_2 > 0 but vice versa is not necessarily allowed.
So, electron capture is not necessary for positron emission.
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