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NCERT Class XII Chemistry
Chapter - General Principle of Process of Isolation of Elements
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Question : 5 of 31
Marks: +1, -0
Out of C and CO, which is a better reducing agent at 673 K?
Solution:  
When carbon acts as a reducing agent, it is either converted into CO\mathrm{CO}or CO2\mathrm{CO}_2 or both.
2C+O2→2CO2 \mathrm{C} + \mathrm{O}_2 \rightarrow 2 \mathrm{CO}
C+O2→CO2\mathrm{C} + \mathrm{O}_2 \rightarrow \mathrm{CO}_2
CO\mathrm{CO} is oxidised to CO2\mathrm{CO}_2 when it is used as a reducing agent.
2CO+O2→2CO22 \mathrm{CO} + \mathrm{O}_2 \rightarrow 2 \mathrm{CO}_2
From the Ellingham diagram (refer answer number 3), it is clear thatat the temperature 673 K, the ΔG° of the formation of CO2\mathrm{CO}_2 from CO ismore negative than the formation of CO or CO2\mathrm{CO}_2 from carbon. Hence, attemperature 673 K, CO is a better reducing agent than C.
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