Concept:Periodic trends in ionization enthalpy, ionic radii, density, and bond energy are evaluated for given statements.
Explanation:For option A:
Carbon has configuration
1s22s22p2.
Its singly charged ion
C+ has
1s22s22p1.
Boron has
1s22s22p1.
Its
B+ has
1s22s2 (filled
2s subshell).
Removing an electron from
B+ requires more energy due to the stable filled subshell.
Thus second ionization enthalpy of carbon is less than that of boron.
Option A is correct.
For option B:
Al3+,
Mg2+,
Na+ are isoelectronic (10 electrons each).
Ionic radius decreases as nuclear charge increases.
Proton numbers: Al = 13, Mg = 12, Na = 11.
Hence size order:
Al3+<Mg2+<Na+.
Option B is correct.
For option C:
Actual densities: Na =
0.97Â g/cm3, K =
0.86Â g/cm3.
Sodium is denser than potassium, so the given statement is incorrect.
For option D:
Bond energies: H–H =
435.88 kJ/mol, F–F =
155Â kJ/mol.
The F–F bond is weaker due to lone pair repulsion on small fluorine atoms.
Thus the statement "H–H bond is weaker than F–F bond" is incorrect.
Answer:Options A and B are correct.