1st MethodQ=ΔU+WQ=2fnRΔT+nRΔT=(2f+1)nRΔTIf f=2⇒Q=2nRΔT⇒2×1×8.3×1.2=19.92(No option is matching)If f=5⇒Q=3.5nRΔT⇒3.5×1×8.3×1.2=34.86(No option is matching)2nd MethodQ=ΔU+WQ=2fnRΔT+PΔVIf f=2⇒Q=nRΔT+PΔV=1×8.3×1.2+105×25×10−3×4×10−4=10.96(No option is matching)If f = 5⇒Q=2.5nRΔT+PΔV2.5×1×8.3×1.2+105×25×10−3×4×10−4=25.9(closest is 25)