CBSE Class 12 Chemistry 2014 Outside Delhi Set 1 Solved Paper

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Question : 24
Total: 30
(a) Draw the structure of major monohalo products in each of the following reactions:
(b) Which halogen compound in each of the following pairs will react faster in SN2 reaction:
(i) CH3‌Br or CH3I
(ii) (CH3)3C−Cl or CH3−Cl
Solution:  
(a) (i) C6H5−CH2−Cl (ii)
(b) (i) The steric barrier surrounding the target atom affects the rate of the SN2 reaction. As CH3I presents less of a barrier, it will undergo the SN2 reaction more quickly than CH3‌Br.
(ii) Since CH3‌Cl is the major halide, it hinders OH− stability to act less, allowing it to react with SN2 more readily than (CH3)3‌CCl.
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