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Question : 24
Total: 30
(a) Draw the structure of major monohalo products in each of the following reactions:S N 2 reaction:
(i)CH 3 Br or CH 3 I
(ii)( CH 3 ) 3 C − Cl or CH 3 − Cl
(b) Which halogen compound in each of the following pairs will react faster in
(i)
(ii)
Solution:
(a) (i) C 6 H 5 − CH 2 − Cl (ii) S N 2 reaction. As CH 3 I presents less of a barrier, it will undergo the S N 2 reaction more quickly than CH 3 Br .
(ii) SinceCH 3 Cl is the major halide, it hinders OH − stability to act less, allowing it to react with S N 2 more readily than ( CH 3 ) 3 CCl .
(b) (i) The steric barrier surrounding the target atom affects the rate of the
(ii) Since
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