CBSE Class 12 Chemistry 2014 Outside Delhi Set 1 Solved Paper

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Question : 24
Total: 30
(a) Draw the structure of major monohalo products in each of the following reactions:
(b) Which halogen compound in each of the following pairs will react faster in SN2 reaction:
(i) CH3Br or CH3I
(ii) (CH3)3CCl or CH3Cl
Solution:  
(a) (i) C6H5CH2Cl (ii)
(b) (i) The steric barrier surrounding the target atom affects the rate of the SN2 reaction. As CH3I presents less of a barrier, it will undergo the SN2 reaction more quickly than CH3Br.
(ii) Since CH3Cl is the major halide, it hinders OH stability to act less, allowing it to react with SN2 more readily than (CH3)3CCl.
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