CBSE Class 12 Chemistry 2016 Delhi Set 1 Solved Paper

© examsnet.com
Question : 17
Total: 26
Give reasons:
(i) Mn shows the highest oxidation state of +7 with oxygen but with fluorine it shows the highest oxidation state of +4 .
(ii) Transition metals show variable oxidation states.
(iii) Actinoids show irregularities in their electronic configurations.
Solution:  
(i) Ability of oxygen to form multiple bond / pπ dπ bond.
(ii) Partially filled d-orbitals / due to comparable energies of ns and (n1)d-orbitals.
(iii) due to relative stabilities of the f,f7 and f4 occupancies of the 5 -orbitals / Comparable energies of 7s,6d,5f-orbitals.
© examsnet.com
Go to Question: