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Question : 17
Total: 26
Give reasons:
(i) Mn shows the highest oxidation state of +7 with oxygen but with fluorine it shows the highest oxidation state of +4 .
(ii) Transition metals show variable oxidation states.
(iii) Actinoids show irregularities in their electronic configurations.
(i) Mn shows the highest oxidation state of +7 with oxygen but with fluorine it shows the highest oxidation state of +4 .
(ii) Transition metals show variable oxidation states.
(iii) Actinoids show irregularities in their electronic configurations.
Solution:
(i) Ability of oxygen to form multiple bond / p π − d π bond.
(ii) Partially filledd -orbitals / due to comparable energies of n s and ( n − 1 ) d -orbitals.
(iii) due to relative stabilities of thef , f 7 and f 4 occupancies of the 5 -orbitals / Comparable energies of 7 s , 6 d , 5 f -orbitals.
(ii) Partially filled
(iii) due to relative stabilities of the
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