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Question : 18
Total: 27
Give the reasons for following:
(i) Transition elements and their compounds act as catalysts.
(ii)E ∘ value for ( Mn 2 + ∕ Mn ) is negative whereas for ( Cu 2 + ∕ Cu ) is positive.
(iii) Actinoids show irregularities in their electronic configuration.
(i) Transition elements and their compounds act as catalysts.
(ii)
(iii) Actinoids show irregularities in their electronic configuration.
Solution:
(i) Transition metals have the ability to adsorb many other substances on their surface and activate them as a result of chemisorption. Transition metals also exhibit a variety of oxidation states, and can change oxidation states relatively easily. This makes transition metals and their compounds good catalysts.
(ii)E o values are indicative of the stability of the oxidized form of the element. The lower the E ∘ value, more stable the oxidized form of the element. Mn 2 + with a half filled d-subshell ( d 5 ) is stable, so Mn is easily oxidized to Mn 2 + , making the E o value negative. Cu 2 + with a partially filled d subshell ( d 9 ) is not stable, and is relatively easily reduced to element form. This makes its E ∘ value positive.
(iii) The electronic configurations of actinoids show irregularities because the energies of their5 f , 6 d , and 7 s -orbitals are close to each other. Electrons can easily move between these subshells.
(ii)
(iii) The electronic configurations of actinoids show irregularities because the energies of their
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