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CBSE Class 12 Chemistry 2023 All Sets Solved Paper

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Question : 13 of 18
Marks: +1, -0
The following experimental rate data were obtained for a reaction carried out at 25C:
A(g)+B(g)C(g)+D(g)
Initial [A(g)]moldm3Initial [B(g)]moldm3Initial rate/mol dm3s1
3.0×1022.0×1021.89×104
3.0×1024.0×1021.89×104
6.0×1024.0×1027.56×104

What are the orders with respect to A(g) and B(g) ?
Solution:  
Let say, rate of reaction = K[A]x[B]y.
then,
1.89×104 = K[3.0×102]x[2×102]y _____(i)
1.89×104=K[3×102]x[4×102]y _____(ii)
and 7.56×104=K[6×102]x[4×102]y _____(iii)
from equation (i) and (ii) , [ii÷i] we got
1=2y
2=2y
y=0
from equation [iii÷ii], we got
4=2x
22=2x
x=2
therefore, the order of reaction with respect to A = 2 and w.r.to B = O
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