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Question : 5
Total: 7
Calculate the de Broglie wavelength associated with the electron in the 2 nd excited state of hydrogen atom. The ground state energy of the hydrogen atom is 13.6 eV .
Solution:
The energy of the n th state of Hydrogen atom
= E n =
For ground state,n = 1
When atom is in second excited state,n = 3
∴ E =
− 1.51 eV
Now, the de Broglie wavelength associated with an electron is
λ =
h = Planck's constant
p = Momentum of electron
m = Mass of electron
p = √ 2 m E
∴ λ =
Or λ =
Or, λ =
∴ λ =
= 0.995 × 10 9 m
= 9.95 A ∘
For ground state,
When atom is in second excited state,
Now, the de Broglie wavelength associated with an electron is
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