NCERT Class XI Chemistry Classification of Elements and Periodicity in Properties Solutions
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Question : 15
Total: 40
Energy of an electron in the ground state of the hydrogen atom is –2.18 × 10 – 18 J. Calculate the ionization enthalpy of atomic hydrogen in terms of J m o l – 1 . [Hint : Apply the idea of mole concept to derive the answer]
Solution:
Energy of the electron in the ground state of H-atom, E 1 = –2.18 × 10 – 18 J
Ionisation energy =E ∞ – E n
Ionisation enthalpy per mole of atomic hydrogen = (E ∞ – E 1 ) NA
= [0 – (– 2.18 ×10 – 18 )] × 6.023 × 10 23
= 2.18 × 6.023 ×10 5 J/mol = 13.13 × 10 5 J/mol
= 1.313 ×10 6 J/mol
Ionisation energy =
Ionisation enthalpy per mole of atomic hydrogen = (
= [0 – (– 2.18 ×
= 2.18 × 6.023 ×
= 1.313 ×
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