NCERT Class XI Chemistry Classification of Elements and Periodicity in Properties Solutions

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Question : 15
Total: 40
Energy of an electron in the ground state of the hydrogen atom is –2.18 × 1018 J. Calculate the ionization enthalpy of atomic hydrogen in terms of Jmol1. [Hint : Apply the idea of mole concept to derive the answer]
Solution:  
Energy of the electron in the ground state of H-atom, E1 = –2.18 × 1018 J
Ionisation energy = EEn
Ionisation enthalpy per mole of atomic hydrogen = (EE1) NA
= [0 – (– 2.18 × 1018)] × 6.023 × 1023
= 2.18 × 6.023 × 105 J/mol = 13.13 × 105 J/mol
= 1.313 × 106 J/mol
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