NCERT Class XI Chemistry Classification of Elements and Periodicity in Properties Solutions

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Question : 18
Total: 40
What are the various factors due to which the ionization enthalpy of the main group elements tends to decrease down a group?
Solution:  
We have to consider two factors : (i) the attraction of electrons towards the nucleus, and (ii) the repulsion of electrons from each other. The effective nuclear charge experienced by a valence electron in an atom will be less than the actual charge on the nucleus because of shielding or screening of the valence electron from the nucleus by the intervening core electrons. As we descend the group, the outermost electron being increasingly farther from the nucleus, there is an increased shielding of the nuclear charge by the electrons in the inner levels. The increase in shielding outweighs the increasing nuclear charge and the removal of the outermost electron requires less energy down a group.
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