NCERT Class XI Chemistry Structure of Atom Solutions

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Question : 16
Total: 67
(i) The energy associated with the first orbit in the hydrogen atom is –2.18 × 1018Jatom1. What is the energy associated with the fifth orbit?
(ii) Calculate the radius of Bohr’s fifth orbit for hydrogen atom.
Solution:  
(i) Energy associated with nth orbit in hydrogen atom is
En =
2.18×1018
n2
J
atom1

∴ Energy associated with 5th orbit is
E5 =
2.18×1018
52
= - 8.72 × 1020Jatom1
(ii) Radius of Bohr’s fifth orbit for hydrogen atom, rn = 0.529 n2 Å
r5 = 0.529 × 52 Å
r5 = 13.225 Å = 13.225 × 1010 m [Since 1 Å = 1010 m]
= 1.3225 × 109 m = 1.3225 nm [Since 1 nm = 109 m]
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