NCERT Class XI Chemistry The s-Block Elements Solutions
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Question : 29
Total: 32
How would you explain the following observations?
(i) BeO is almost insoluble butB e S O 4 is soluble in water.
(ii) BaO is soluble butB a S O 4 is insoluble in water.
(iii) LiI is more soluble than KI in ethanol.
(i) BeO is almost insoluble but
(ii) BaO is soluble but
(iii) LiI is more soluble than KI in ethanol.
Solution:
(i) BeO is almost insoluble in water as it is covalent in nature and tightly held together in the solid state while B e S O 4 is highly soluble in water due to high energy of solvation of smaller B e 2 + ion.
(ii) The size ofO 2 – ion is much smaller than that of the S O 4 2 − ion. Since a bigger anion stabilises a bigger cation more than a smaller anion therefore, the lattice energy of BaO is much smaller than that of B a S O 4 and hence BaO is soluble while B a S O 4 is insoluble in water.
(iii) LiI having much more covalent character than KI because of small size of Li+ as compared toK + . Hence, LiI is more soluble in ethanol.
(ii) The size of
(iii) LiI having much more covalent character than KI because of small size of Li+ as compared to
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