NCERT Class XII Chemistry
Chapter - Alcohols, Phenols and Ethers
Questions with Solutions

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Question : 44
Total: 45
Which of the following is an appropriate set of reactants for the preparation of 1-methoxy-4-nitrobenzene and why?
Solution:  
Set (ii) is more appropriate for preparation of the said compound. In set (i) the CH3O acts as a nucleophile. But, the presence of bulky
group prevents the nucleophilic attack.
In set (ii) nucleophile,
attacks CH3Br and the desired product
is formed.
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