NCERT Class XII Chemistry
Chapter - Coordination Compounds
Questions with Solutions
© examsnet.com
Question : 40
Total: 43
Explain [ C o ( N H 3 ) 6 ] 3 + is an inner orbital complex whereas [ N i ( N H 3 ) 6 ] 2 + is an outer orbital complex.
Solution:
In the presence of NH3, the 3d electrons pair up leaving two d orbitalsempty to be involved in d 2 s p 3 hybridisation forming inner orbital complexin case of [ C o ( N H 3 ) 6 ] 3 + .
In[ N i ( N H 3 ) 6 ] 2 + , Ni is in +2 oxidation state and has d3 configuration, thehybridisation involved is sp3 d2 forming outer orbital complex.
In
© examsnet.com
Go to Question: