NCERT Class XII Chemistry
Chapter - Haloalkanes and Haloarenes
Questions with Solutions
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Question : 17
Total: 31
Out of C 6 H 5 C H 2 C l and C 6 H 5 C H C l C 6 H 5 , which is more easily hydrolysed by aqueous KOH?
Solution:
(a) Hydrolysis of an alkyl halide is an example of nucleophilic substitution reaction. In case of aryl halides this follows the
(b)
(c) Out of I & II, carbocation II is more stable. The reason is the presence of two phenyl rings attached to the carbon carrying the positive charge.
(d) As a result, the delocalisation of the +ve charge is greater and the carbocation is more stable. Due to this, (II) is formed faster and the corresponding halide is hydrolysed with greater ease as compared to benzyl chloride.
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