NCERT Class XII Chemistry
Chapter - The d- and f-Block Elements
Questions with Solutions
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Question : 13
Total: 49
How is the variability in oxidation states of transition metals different from that of the non-transition metals ? Illustrate with examples.
Solution:
The variability of oxidation states, a characteristic of transitionelements, arises out of incomplete filling of d-orbitals in such a way thattheir oxidation states differ from each other by unity, e . g . , V I I , V I I I , V I V , V V .This is in contrast with the variability of oxidation sates of non transitionelements where oxidation states normally differ by a unit of two.
In the p-block the lower oxidation states are favoured by the heaviermembers (due to inert pair effect), the opposite is true in the groupsof d-block. For example, in group 6, Mo(VI) and W(VI) are found to bemore stable than Cr(VI). Thus Cr(VI) in the form of dichromate in acidicmedium is a strong oxidising agent, whereasM o O 3 and W O 3 are not.
In the p-block the lower oxidation states are favoured by the heaviermembers (due to inert pair effect), the opposite is true in the groupsof d-block. For example, in group 6, Mo(VI) and W(VI) are found to bemore stable than Cr(VI). Thus Cr(VI) in the form of dichromate in acidicmedium is a strong oxidising agent, whereas
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