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NCERT Class XII Chemistry
Chapter - The p-Block Elements
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Question : 10 of 74
Marks: +1, -0
Why does R3P=OR_3\mathrm{P}=\mathrm{O} exist but R3N=OR_3\mathrm{N}=\mathrm{O} does not (R = alkyl group)?
Solution:  
In R3N=OR_3\mathrm{N}=\mathrm{O}, covalency required is five. The maximum covalency ofnitrogen is four as it does not possess d-orbitals in the valence shell i.e., itcannot extend its valency beyond four. On the other hand, other membershave d-orbitals and can utilise these orbitals to show covalency of five orsix e.g., R3P=O,PCl5,[SbF6]\text{e.g., } R_3\mathrm{P}=\mathrm{O}, \mathrm{PCl}_5, [\mathrm{SbF}_6]^{-}, etc. These can form dπpπd\pi - p\pi bonds.
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