(1) 2NaN3Δ2Na+3N2 (2) (NH4)2Cr2O7ΔCr2O3+N2+4H2O (3) The reaction of ammonium chloride with calcium hydroxide form CaCl2 instead of N2 as shown below. 2NH4Cl+Ca(OH)2→CaCl2+2NH4OH (4) Ba(N3)2ΔBa+3N2 Therefore, reaction (3) does not liberate N2