Concept:In acidic medium, manganate ion undergoes disproportionation.Explanation:MnO42− is unstable in acidic solution.It disproportionates into permanganate ion and manganese dioxide.Balanced reaction:3MnO42−+4H+→2MnO4−+MnO2+2H2OThus, the products are MnO4− and MnO2.Answer:Option A: MnO4− and MnO2