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Test Index
Heat and Thermodynamics
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Section:
Physics
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© examsnet.com
Question : 47 of 73
Marks:
+1
,
-0
A container of fixed volume has a mixture of one mole of hydrogen and one mole of helium in equillibrium at temperature T. Assuming the gases are ideal the correcr statemnt(s) is (are )
[JEE Adv 2015 P1]
The average energy per mole of the gas mixture is 2RT
The ratio of speed of sound of i the gas mixture to that in helium gas is
6
5
\sqrt{\frac{6}{5}}
5
6
.
The ratio of the rms speed of helium atoms to that hydrogen molecules is
1
2
\frac{1}{2}
2
1
The ratio of the rms speed of helium atoms to that hydrogen molecules is
1
2
\frac{1}{\sqrt{2}}
2
1
Validate
Solution:
U
=
n
C
v
1
T
+
n
C
v
2
T
U=nC_{v_1}T+nC_{v_2}T
U
=
n
C
v
1
T
+
n
C
v
2
T
=
1
×
5
2
R
T
+
3
2
R
T
=
4
R
T
=1\times\frac{5}{2}RT+\frac{3}{2}RT=4RT
=
1
×
2
5
RT
+
2
3
RT
=
4
RT
⇒
2
C
V
m
i
x
T
=
4
R
T
\Rightarrow 2C_{V_{mix}}T=4RT
⇒
2
C
V
mi
x
T
=
4
RT
Average energy per mole
=
2
R
T
⇒
C
V
m
i
x
=
2
R
=2RT\Rightarrow C_{V_{mix}}=2R
=
2
RT
⇒
C
V
mi
x
=
2
R
C
m
i
x
C
H
o
=
(
γ
m
i
x
γ
H
o
)
(
M
H
e
M
m
i
x
)
=
\frac{C_{mix}}{C_{Ho}}=\sqrt{\left(\frac{\gamma_{mix}}{\gamma_{Ho}}\right)\left(\frac{M_{He}}{M_{mix}}\right)}=
C
Ho
C
mi
x
=
(
γ
Ho
γ
mi
x
)
(
M
mi
x
M
He
)
=
3
2
×
3
5
×
4
3
=
6
5
\sqrt{\frac{3}{2}\times\frac{3}{5}\times\frac{4}{3}}=\sqrt{\frac{6}{5}}
2
3
×
5
3
×
3
4
=
5
6
V
r
m
s
H
e
V
r
m
s
H
2
\frac{V_{rms}\mathrm{He}}{V_{rms}\mathrm{H}_2}
V
r
m
s
H
2
V
r
m
s
He
=
M
H
2
M
H
e
=
1
2
=\sqrt{\frac{M_{\mathrm{H}_2}}{M_{\mathrm{He}}}}=\frac{1}{\sqrt{2}}
=
M
He
M
H
2
=
2
1
© examsnet.com
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