Concept:Brewster's law states that light reflected from a boundary is completely polarized when the reflected and refracted rays are perpendicular to each other.Explanation:The reflected ray CD is polarized when the angle of incidence at the final boundary (water to prism) satisfies Brewster's law.At that boundary, the initial medium is water (nw=34) and the final medium is prism (np=34).Using Brewster's law: tanθ=nwnp=4/34/3=33=3.Since tan60∘=3, the angle of incidence at the bottom water–prism interface is θ=60∘.Now apply Snell's law sequentially through the layers: water → glass → water → prism.At the top water–glass boundary: nwsini=ngsinrg.At the glass–water boundary: ngsinrg=nwsinrw.At the bottom water–prism boundary: nwsinrw=npsinrp.Combining all gives nwsini=nwsinθ, so sini=sinθ.Since θ=60∘, we obtain i=60∘.