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JEE Main 16 March 2021 Shift 2 Solved Paper
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Question : 42
Total: 90
Ammonolysis of alkyl halides followed by the treatment with
N
a
O
H
solution can be used to prepare primary, secondary and tertiary amines. The purpose of
N
a
O
H
in the reaction is
[16 Mar 2021 Shift 2]
to remove basic impurities
to activate
N
H
3
used in the reaction
to remove acidic impurities
to increase the reactivity of alkyl halide
Validate
Solution:
Ammonolysis of alkyl halides
R
−
X
N
H
3
─
─
>
−
H
X
R
−
N
H
2
R
−
X
─
─
>
−
H
X
R
2
N
H
R
−
X
─
─
>
−
H
X
R
3
N
R
X
─
─
>
R
4
⊕
N
⊖
X
During the reaction
H
X
(acid) is formed. Hence, we use
N
a
O
H
to remove this acidic impurities.
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