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KCET 2023 Chemistry Solved Paper
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© examsnet.com
Question : 57
Total: 60
If a didentate ligand ethane
−
1
,
2
- diamine is progressively added in the molar ratio en :
Ni
:
:
1
:
1
,
2
:
1
,
3
:
1
to
[
Ni
(
H
2
O
)
6
]
2
+
aq solution, following co-ordination entities are formed.
I.
[
Ni
(
H
2
O
)
4
en
]
(
aq
)
2
+
-pale blue
II.
[
Ni
(
H
2
O
)
2
(
en
)
2
]
(
aq
)
2
+
-blue/purple
III.
[
Ni
(
en
)
3
]
(
aq
)
2
+
-violet
The wavelength in
nm
of light absorbed in case of I and III are rsepctively
310
nm
and
500
nm
600
nm
and
535
nm
475
nm
and
310
nm
300
nm
and
475
nm
Validate
Solution:
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