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Manipal Entrance Test 2014 Chemistry Paper
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© examsnet.com
Question : 55
Total: 60
The complex
[
Fe
(
H
2
O
)
5
NO
]
2
+
is formed in thering test for nitrate ion when freshly prepared FeSO
4
solution is added to aqueous solution of
NO
3
−
followed by addition of Conc.
H
2
SO
4
. This complex is formed by charge transfer in which
Fe
2
+
changes to Fe
3
+
and NO+ changes to NO
Fe
2
+
changes to Fe
3
+
and NO changes to NO+
Fe
2
+
changes to Fe
+
and NO changes to NO
+
No charge transfer takes place
Validate
Solution:
Fe
2
+
+
e
−
→
Fe
+
NO
→
NO
+
+
e
−
Based on magnetic properties of the complex, it is found that iron has three unpaired electrons thus it exists as
F
e
+
formed by reduction of
F
e
2
+
by NO which is oxidised to NO
+
© examsnet.com
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