Concept:A strong acid like HCl ionises completely in water, so its hydrogen ion concentration equals the acid concentration. The pOH is then found using the relationship between pH and pOH at
25∘C.
Explanation:HCl is a strong acid, so it undergoes complete ionisation in aqueous solution.
For
0.001M HCl, the concentration of hydrogen ions is:
[H+]=0.001=10−3MNow, calculate the pH of the solution using the formula:
pH=−log[H+]Substitute the value of
[H+]:
pH=−log(10−3)=3At
25∘C, the ion product of water gives the relation:
pH+pOH=14Rearranging for pOH:
pOH=14−pHSubstitute the calculated pH value:
pOH=14−3=11Therefore, the pOH of the given HCl solution is 11.
Answer:Option A: 11