Concept:Silver crystallises in a face-centered cubic (FCC) lattice. For FCC, the number of atoms per unit cell is
Z=4.
The density of the crystal is calculated using the unit cell volume and molar mass through the standard formula.
Explanation:The density formula for a crystalline solid is written as:
<br>ρ=NA×a3Z×M<br>Here, the values are substituted as follows:
Z=4,
M=108 gmol−1,
NA=6.022×1023, and
a3=6.84×10−23 cm3.
Plugging these into the formula:
<br>ρ=6.022×1023×6.84×10−234×108<br>The powers of ten cancel out, giving:
<br>ρ=6.022×6.84432<br>This simplifies to:
<br>ρ=41.19432≈10.49 gcm−3<br>Hence, the density of silver is
10.49 gcm−3.
Answer:10.49 gcm−3 — Option B.