Concept:EAN is the total number of electrons around the central metal ion, which is the sum of electrons on the metal and electrons donated by ligands.
Explanation:For
[Cu(NH3)4]2+, the atomic number of copper is
Z=29.
Since
NH3 is a neutral ligand, the oxidation state of Cu in this complex is
+2.
So the number of electrons remaining on the
Cu2+ ion is
29−2=27.
Each
NH3 ligand donates one lone pair, which contributes 2 electrons.
Total electrons donated by 4 ligands
=4×2=8.
Therefore, EAN is calculated as:
EAN=(29−2)+(4×2)=27+8=35Answer:The EAN of the metal ion is 35, which corresponds to Option A.