Concept:A terminal alkyne has the triple bond at the end of the carbon chain, forming the terminal group
−C≡CH.
Explanation:To identify a terminal alkyne, check whether a hydrogen atom is directly attached to a triple-bonded carbon.
Ethyne:
HC≡CH. Both triple-bonded carbons carry hydrogen atoms, so it is a terminal alkyne.
Propyne:
CH3​−C≡CH. The triple bond is between carbon 1 and carbon 2, with a terminal hydrogen, so it is terminal.
But-1-yne:
CH3​−CH2​−C≡CH. The triple bond starts from carbon 1, so it is terminal.
But-2-yne:
CH3​−C≡C−CH3​. The triple bond lies in the middle of the chain, and no triple-bonded carbon carries a hydrogen atom.
Hence, But-2-yne lacks the terminal
−C≡CH group, so it is NOT a terminal alkyne.
Answer:Option D: But-2-yne