Concept:The oxidation number is determined using known oxidation states of hydrogen and oxygen, then solving for chlorine in a neutral molecule.
Explanation:In
HOClO2, there are 1 hydrogen atom, 1 chlorine atom, and 3 oxygen atoms.
Hydrogen has an oxidation number of
+1.
Oxygen has an oxidation number of
−2.
Let the oxidation number of chlorine be
x.
The molecule is neutral, so the total sum of oxidation numbers is zero.
(+1)+x+3(−2)=01+x−6=0x−5=0x=+5Therefore, the oxidation number of Cl in
HOClO2 is
+5.
Answer:+5, which matches option B.