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MHTCET 2016 Chemistry Solved Paper
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© examsnet.com
Question : 50
Total: 50
Primary nitroalkanes are obtained in good yield by oxidising aldoximes with the help of
trifluoroperoxy acetic acid
acidified potassium permanganate
concentrated nitric acid
potassium dichromate and dilute sulphuric acid
Validate
Solution:
(a) Primary nitroalkanes are obtained in good yield by oxidising aldoximes with the help of trifluoroperoxy acetic add.
RCH = NOH (Aldoxime)
[
O
]
→
C
F
3
C
O
O
O
H
RCH =
O
−
|
N
+
- OH ⇌
R
C
H
2
N
O
2
(1°nitro alkane)
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