Concept:ClF3 has 5 electron pairs around the central chlorine atom (3 bond pairs, 2 lone pairs) according to VSEPR theory.
Chemical Equation / Formula:ClF3 → Central atom Cl with 7 valence electrons, each F contributes 1 electron, plus 1 extra electron from the negative charge? Actually neutral: Cl has 7 valence e⁻, each F contributes 1, total 10 e⁻ = 5 pairs. 3 bond pairs with F, 2 lone pairs on Cl.
Explanation:The central Cl atom in
ClF3 undergoes
sp3d hybridization.
The five electron pairs arrange in a trigonal bipyramidal geometry.
The two lone pairs occupy equatorial positions to minimise repulsion.
The three F atoms occupy the remaining positions, giving a T-shaped molecular geometry.
Thus, the molecule has a T-shape with two lone pairs on Cl.
Shortcut:VSEPR type
AX3E2 (A = central atom, X = bonded atoms, E = lone pairs) always gives T-shaped geometry.
Answer:Option A is correct: It has T-shaped geometry with two lone pairs on Cl atom.