Only coloured salts on heating with the glassy borax bead form coloured metaborates in oxidising flame.Na2​B4​O7​⋅10H2​OΔ​Na2​B4​O7​Δ​Glassy bead2NaBO2​+B2​O3​​Coloured salt +B2​O3​→Coloured metaborate Sodium salts are colourless and hence do not give a positive test.Chromium - GreenIron - GreenCobalt - Blue