Concept:In electrolytic refining, the impure metal acts as the anode while a pure metal strip serves as the cathode.
Explanation:Electrolytic refining purifies metals like copper, zinc, and silver using electrolysis.
The anode is made of the impure metal that needs to be refined.
The cathode is a thin sheet of the pure metal.
The electrolyte is a soluble salt solution of the same metal, e.g., acidified copper sulfate (
CuSO4) for copper refining.
When electric current passes, the impure metal at the anode dissolves as metal ions:
M→Mn++ne−.
These ions move through the electrolyte and deposit on the pure metal cathode:
Mn++ne−→M.
Impurities either dissolve in the electrolyte or settle as anode mud at the bottom.
Thus, only the impure metal can dissolve and allow purification.
Using a graphite rod or inert electrode would not supply the metal ions needed for deposition.
A pure metal strip is used as the cathode, not the anode.
Therefore, the anode must be a strip of impure metal.
Answer:A strip of impure metal to be refined