TS EAMCET 18-July-2022 Shift 1 Solved Paper

(i) Reaction of HBr with propene in the presence of peroxide gives n -propyl bromide. This addition reaction is an example of an anti-Markownikoff's addition reaction.
‌R−O−O−R‌

∆

⟶

2R−O∘
‌2R−O∘+H−Br⟶R−OH+Br∘


(ii) Reaction of n-propyl bromide with Mg gives propyl magnesium bromide (Grignard reagent).

CH3CH2CH2‌Br

Propyl bromide

+Mg⟶CH3CH2CH2‌MgBr
(iii) Reaction of propyl magnesium bromide with propanal gives nucleophilic additon reaction.

(iv) Reaction of hexan-3-ol with oxidising agent CrO3 .