Concept:Monatomic elements exist as single atoms in their standard state due to a stable electron configuration.Explanation:Helium (He) is a noble gas with a full outer shell of 2 electrons.It does not need to bond with other atoms to become stable.Thus, it is naturally monatomic.Hydrogen (H2​) exists as diatomic molecules in its elemental form.Sulphur typically forms S8​ rings (octatomic).Phosphorus exists as P4​ molecules (tetratomic).Only helium among the given options is monatomic.Answer:D. Helium