Concept:Isoelectronic species are atoms or ions that have the same number of electrons.
Explanation:First, find the number of electrons in
Cl−.
Chlorine atom (atomic number 17) has 17 electrons.
Gaining one electron gives
Cl− with
17+1=18 electrons.
Now count electrons for each option:
K+: Potassium atom (atomic number 19) has 19 electrons. Losing one electron gives
19−1=18 electrons. Isoelectronic with
Cl−.
Mg2+: Magnesium atom (atomic number 12) has 12 electrons. Losing two electrons gives
12−2=10 electrons. Not isoelectronic with
Cl−.
S2−: Sulfur atom (atomic number 16) has 16 electrons. Gaining two electrons gives
16+2=18 electrons. Isoelectronic.
P3−: Phosphorus atom (atomic number 15) has 15 electrons. Gaining three electrons gives
15+3=18 electrons. Isoelectronic.
Thus, only
Mg2+ has a different electron count (10) from
Cl− (18).
Answer:Option B:
Mg2+