Concept:In metal carbonyls, carbon monoxide (CO) is a neutral ligand, so its oxidation state is taken as 0. The overall charge on the molecule is zero.Explanation:Let the oxidation state of Iron in Fe(CO)5 be x.Since each CO contributes 0, the total contribution from five CO is 0×5=0.The sum of oxidation states in a neutral molecule equals zero: x+0=0.Thus, x=0.Answer:The oxidation state of Iron in Fe(CO)5 is 0, which corresponds to option A.