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Test Index
VITEEE 2017 Paper
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Section:
Chemistry
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© examsnet.com
Question : 52 of 125
Marks:
+1
,
-0
1 -Propanol and 2-propanol can be distinguished by
oxidation with alkaline
K
M
n
O
4
\mathrm{KMnO_4}
KMn
O
4
followed by reaction with Fehling solution
oxidation with acidic dichromate followed by reaction with Fehling solution
oxidation by heating with copper followed by reaction with Fehling solution
oxidation with concentrated
H
2
S
O
4
\mathrm{H_2SO_4}
H
2
S
O
4
followed by reaction with Fehling solution
Validate
Solution:
C
H
3
C
H
2
C
H
2
O
H
\mathrm{CH_3CH_2CH_2OH}
C
H
3
C
H
2
C
H
2
OH
→
or
K
2
C
r
2
O
7
/
H
+
alk.
K
M
n
O
4
\xrightarrow[\text{or } \mathrm{K_2Cr_2O_7}/\mathrm{H}^{+}]{\text{alk. } \mathrm{KMnO_4}}
alk.
KMn
O
4
or
K
2
C
r
2
O
7
/
H
+
C
H
3
C
H
2
C
H
O
\mathrm{CH_3CH_2CHO}
C
H
3
C
H
2
CHO
→
C
H
3
C
H
2
C
O
O
H
\mathrm{CH_3CH_2COOH}
C
H
3
C
H
2
COOH
→
Felhing soln
\xrightarrow{\text{Felhing soln}}
Felhing soln
No reaction
(b)
C
H
3
C
H
O
C
H
3
\mathrm{CH_3CHOCH_3}
C
H
3
CHOC
H
3
→
or
K
2
C
r
2
O
7
/
H
+
alk.
K
M
n
O
4
\xrightarrow[\text{or } \mathrm{K_2Cr_2O_7}/\mathrm{H}^{+}]{\text{alk. } \mathrm{KMnO_4}}
alk.
KMn
O
4
or
K
2
C
r
2
O
7
/
H
+
C
H
3
C
O
C
H
3
\mathrm{CH_3COCH_3}
C
H
3
COC
H
3
→
C
H
3
C
O
O
H
\mathrm{CH_3COOH}
C
H
3
COOH
→
Feh sol.
\xrightarrow{\text{Feh sol.}}
Feh sol.
No reaction
(c)
C
H
3
C
H
2
C
H
2
O
H
\mathrm{CH_3CH_2CH_2OH}
C
H
3
C
H
2
C
H
2
OH
→
C
u
\xrightarrow{\mathrm{Cu}}
Cu
C
H
3
C
H
2
C
H
O
\mathrm{CH_3CH_2CHO}
C
H
3
C
H
2
CHO
→
Fehling solution
\xrightarrow{\text{Fehling solution}}
Fehling solution
C
u
2
O
\mathrm{Cu_2O}
C
u
2
O
(red)
C
H
3
C
H
O
H
C
H
3
\mathrm{CH_3CHOHCH_3}
C
H
3
CHOHC
H
3
→
C
u
\xrightarrow{\mathrm{Cu}}
Cu
C
H
3
C
O
C
H
3
\mathrm{CH_3COCH_3}
C
H
3
COC
H
3
→
Fehling solution
\xrightarrow{\text{Fehling solution}}
Fehling solution
No reaction
(d)
C
H
3
C
H
2
C
H
2
O
H
\mathrm{CH_3CH_2CH_2OH}
C
H
3
C
H
2
C
H
2
OH
or
C
H
3
C
H
O
H
C
H
3
\mathrm{CH_3CHOHCH_3}
C
H
3
CHOHC
H
3
→
Conc.
H
2
S
O
4
\xrightarrow{\text{Conc. } \mathrm{H_2SO_4}}
Conc.
H
2
S
O
4
C
H
3
C
H
=
C
H
2
\mathrm{CH_3CH=CH_2}
C
H
3
CH
=
C
H
2
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