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WBJEE 2012 Chemistry Solved Paper
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© examsnet.com
Question : 35
Total: 40
An equimolar mixture of toluene and chlorobenzene is treated with a mixture of conc.
H
2
S
O
4
and conc.
H
N
O
3
. Indicate the correct statement from the following.
p-nitrotoluene is formed in excess
equimolar amounts of p-nitrotoluene and p-nitrochlorobenzene are formed
p-nitrochlorobenzene is formed in excess
m-nitrochlorobenzene is formed in excess
Validate
Solution:
As toluene and chlorobenzene, both can react with mixture of conc.
H
2
S
O
4
and conc.
H
N
O
3
but being more reactive, toluene will yield p - nitrotoluene in excess
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