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WBJEE 2014 Chemistry Solved Paper
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© examsnet.com
Question : 56
Total: 60
Cupric compounds are more stable than their cuprous counterparts in solid state. This is because
the endothermic character of the 2nd I P of Cu is not so high
size of
C
u
2
+
is less than
C
u
+
C
u
2
+
has stabler electronic configuration as compared to Cu
the lattice energy released for cupric compounds is much higher than
C
u
+
Validate
Solution:
Actually 2nd IP of Cu (1958 kJ/mol) is not very high as compared to 1st IP (745 kJ/mol). In addition the gain inlattice energy due to +2 state and small size f Cu favour the divalent state in the solid.
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